油气田开发中H_2S/CO_2腐蚀研究进展Research progress of H_2S/CO_2 corrosion in oil and gas development
王成达,严密林,赵新伟,李平全,王辉
摘要(Abstract)：
首先分别探讨了CO2腐蚀和H2S腐蚀的机理及其影响因素;进而讨论了H2S/CO2共存条件下的腐蚀机理及其影响因素,分析了国内外H2S/CO2腐蚀研究的现状和趋势,提出了油井管H2S/CO2腐蚀的防护措施,探讨了高酸性油气田腐蚀研究的热点问题及发展方向.
关键词(KeyWords)： 油井管;硫化氢腐蚀;二氧化碳腐蚀;腐蚀防护
基金项目(Foundation):
作者(Author): 王成达,严密林,赵新伟,李平全,王辉
参考文献(References)：
- [1]Schmitt G.Fundamental Aspects of CO2Corrosion[A].Hausler R,Giddard HP.Corrosion[C].Houston,Texas:NACEInternational,1984.No.84010.
- [2]张学元,邸超,雷良才.二氧化碳腐蚀与控制[M].北京:化学工业出版社,2000.15-16.
- [3]Xia Z,Chou K C,Szklarska-Smialowska Z.Pitting Corrosion of Carbon Steel in CO2-Containing NaCl Brine[J].Corrosion,1989,45(8):636-642.
- [4]Rlesenfeld F C,Blohm C L.Corrosion Problems in Gas Purification Units Employing MEA Solutions[J].Petroleum Refiner,1950,29(4):141-150.
- [5]《油气田腐蚀与防护技术手册》编委会.油气田腐蚀与防护技术手册(下册)[M].北京:石油工业出版社,1999.471-492.
- [6]Fierro G,Ingo G M,Mancia F.XPS Investigation on AISI420Stainless Steel Corrosion in Oil and Gas Well Environments[J].Materials Science,1990,25(2B):1407-1415.
- [7]Bol mer P W.Polarization of Iron in H2S-NaHS Buffers[J].Corrosion,1965,21(3):69.
- [8]李鹤林,白真权,刘道新,等.模拟油田H2S/CO2环境中N80钢的腐蚀及影响因素研究[J].材料保护,2003,36(4):32-34.
- [9]冯星安,黄柏宗,高光第.对四川罗家寨气田高含CO2、H2S腐蚀的分析及防腐设计初探[J].石油工程建设,2004,30(1):10-14.
- [10]Dugstad A,Lunde L.Parametric Study of CO2Corrosion of Carbon Steel[A].Hausler R,Giddard H P.Corrosion[C].Houston,Texas:NACE International,1994.No.94014.
- [11]Mora-Mendoza J L,Chacon-Nava J G,Zavala-Olivares,G.Influence of Turbulent Flow on The Localized Corrosion Processes of Mild Steel with Inhibited Aqueous CO2Systems[J].Corrosion,2002,58(7):608-619.
- [12]李国敏.碳钢在含硫化氢及高压二氧化碳饱和的NaCl溶液中的腐蚀行为[J].中国腐蚀与防护学报,2000,20(4):204-209.
- [13]周计明.油管钢在含CO2/H2S高温高压水介质中的腐蚀行为及防护技术的作用[D].西安:西北工业大学,2002.
- [14]Hausler R H.Laboratory Investigations of The CO2Corrosion Mechanism As Applied to Hot Deep Gas Wells[A].Hausler R,Giddard H P.Corrosion[C].Houston,Texas:NACEInternational,1984.No.84072.
- [15]Fierro G,Ingo G M,Mancia F.XPS investigation on the corrosion behavior of13Cr martensitic stainless steel in CO2-H2S-Cl-environments[J].Corrosion,1989,45(10):814-823.
- [16]Videm K,Dugstad A.Effect of flow velocity,pH,Fe2+concentration and steel quality on The CO2corrosion of carbon steels[A].Hausler R,Giddard HP.Corrosion[C].Houston,Texas:NACEInternational,1990.No.90042.
- [17]Masamura K,Hashizume S,Sakai J.polarization behavior of high-alloy OCTG in CO2environment as affected by chlorides and sulfides[J].Corrosion,1987,43(6):359-365.
- [18]李鹤林.石油管工程[M].北京:石油工业出版社,1999.79-80.
- [19]苏俊华,张学元,王凤平,等.高矿化度介质中二氧化碳腐蚀金属的规律[J].材料保护,1998,31(11):21-23.