驱油用表面活性剂的发展及界面张力研究Development of surfactants for enhanced oil recovery factor and study of their interfacial tension
仉莉;吴芳;张弛;刘晓玲;葛际江;张贵才;
摘要(Abstract):
综述了驱油用磺酸盐表面活性剂、羧酸盐表面活性剂、非离子-阴离子两性表面活性剂、烷基多糖苷表面活性剂、Gemini表面活性剂、甜菜碱表面活性剂的发展,指出Gemini表面活性剂、甜菜碱表面活性剂在油田中应用需解决的问题和国外近年较重视驱油用非离子-阴离子表面活性剂的趋势;总结了表面活性剂分子结构与降低界面张力性能的关系,指出研究甜菜碱类表面活性剂低界面张力形成机理对指导新型表面活性剂的合成有重要意义.
关键词(KeyWords): 化学驱油;表面活性剂;提高采收率
基金项目(Foundation): 霍英东教育基金会第十一届高等院校青年教师基金(优选资助课题)资助项目(编号:114016)
作者(Authors): 仉莉;吴芳;张弛;刘晓玲;葛际江;张贵才;
参考文献(References):
- [1]De Groot M.Lignosulfonate sacrificial agents in oil recov-ery:US,1823439[P].1929.
- [2]曹绪龙,何秀娟,赵国庆,等.表面活性剂疏水链长对高温下泡沫稳定性的影响[J].高等学校化学学报,2007,28(11):2106-2111.
- [3]曲景奎,周桂英,朱友益,等.三次采油用烷基苯磺酸盐弱碱体系的研究[J].精细化工,2006,23(1):82-85.
- [4]邹文化,崔正刚,张天林.重烷基苯磺酸盐中试产品的应用性能[J].日用化学工业,2002,32(6):16-19.
- [5]Yang Jie,Qiao Weihong,Li Zongshi.Effects of branchingin hexadecylbenzene sulfonate isomers on interfacial ten-sion behavior in oil/alkali systems[J].Fuel,2005,84:1607-1611.
- [6]Zhao Zhongkui,Bi Chenguang,Qiao Weihong,et al.Dy-namic interfacial tension behavior of the novel surfactantsolutions and Daqing crude oil[J].Colloids and SurfacesA:Physicochem Eng Aspects,2007,294:191-202.
- [7]沈平平.大幅度提高采收率的基础研究[J].中国基础科学,2003(2):9-14.
- [8]郭万奎,杨振宇,伍晓林,等.用于三次采油的新型弱碱表面活性剂[J].石油学报,2007,27(5):75-78.
- [9]Berger P D,Lee C H.Ultra low concentration surfactantsfor sandstone and limestone floods[C].SPE75186,2002.
- [10]韩冬,沈平平.表面活性剂驱油原理及应用[M].北京:石油工业出版社,2001:213-289.
- [11]Ramesh Varadaraj,Jan Bock,Paul Valint.Foundamentalinterfacial properties of alkyl-branched sulfate and ethoxysulfate surfactants derived from guerbet alcohols.1.surfaceand instantaneous interfacial tensions[J].J Phys Chem,1991,95:1671-1676.
- [12]Richard F Tabor,Sarah Gold.Electron density matching asa guide to surfactant design[J].Langmuir,2006,22:963-968.
- [13]王德民.大庆油田“三元”、“二元”、“一元”驱油研究[J].大庆石油地质与开发,2003,22(3):1-9.
- [14]黄宏度,DonnellanⅢW H,Jones J H.用中和烃氧化产物制备高界面活性的驱油剂[J].江汉石油学院学报,1990,12(4):50.
- [15]李干佐,沈强,郑立强,等.新型驱油用表面活性剂天然混合羧酸盐[J].油田化学,1999,16(1):57-59,63.
- [16]李干佐,顾强,毛宏志.天然混合羧酸盐驱油剂在中原油田的应用[J].油田化学,2000,17(4):346-347,358.
- [17]黄宏度,吴一慧,王尤富,等.石油磺酸盐和羧酸盐体系的界面活性[J].油田化学,2000,17(1):69-72.
- [18]Walter Gale W,Maura Puerto C,ThomasAshcraft L,et al.Propoxylate dethoxylated surfactants and method of recove-ring oil therewith:US,4293428[P].1981.
- [19]Michel A M,Djojosoeparto R S,Henk Haas,et al.En-hanced waterflooding design with dilute surfactant concen-trations for north sea conditions[C].SPE 35372,1996.
- [20]Maerker J M,Gale W W.Surfactant flood process designfor Loudon[C].SPE 20218,1992.
- [21]Shekhar Jayanti,Larry NBritto,Varadarajan Dwarakanath.Laboratory evaluation of custom-designed surfactants to re-mediate NAPL source zones[J].Environ Sci Technol,2002,36:5491-5497.
- [22]Wu Y,Shuler P,Blanco M,et al.A study of branched al-cohol propoxylated surfactants for improved oil recovery[C].SPE 95404,2005.
- [23]Levitt D B,Jackson A C,Heinson C.Identification and e-valuation of high-performance EOR surfactants[C].SPE100089,2006.
- [24]Kishore K Mohanty.Dilute surfactant methods for carbon-ate formations[R].DE-FC26-02NT15322,2005.
- [25]王业飞,焦翠,赵福麟.羧甲基化的非离子型表面活性剂与石油磺酸盐的复配试验[J].石油大学学报,1996,20(4):52-55.
- [26]李宜坤,赵福麟,王业飞.以丙酮作溶剂合成烷基酚聚氧乙烯醚羧酸盐[J].石油学报(石油加工),2003,19(2):33-38.
- [27]靳志强,王涵慧,俞稼镛.Guerbet十四醇聚氧乙烯醚硫酸钠的合成与表面活性[J].精细化工,2002,19(8):435-439.
- [28]秦冰.稠油乳化降粘剂结构与性能关系的研究[D].北京:中国石油化工科学研究院,2001.
- [29]马文辉,梁梦兰,袁红,等.稠油低温乳化降粘剂BL-1的研制及反应[J].油田化学,2002,19(2):134-135.
- [30]李明忠,赵国景,张乔良,等.耐盐稠油降粘剂的研制[J].精细化工,2004,21(5):380-384.
- [31]Liu Qiang,Dong Mingzhe,Yue Xiangan,et al.Synergy ofalkali and surfactant in emulsification of heavy oil in brine[J].Colloidsand Surface A:Physicochem Eng Aspects,2006,273:219-228.
- [32]Liu Q,Dong M,Ma S.Alkaline/surfactant flood potentialin Western Candian heavy oil reservoirs[C].SPE 99791,2006.
- [33]Balzer Dieter,Lueders Harald.Process for the extration ofcrude oil for an underground deposite using surfactant:US,4985154[P].1991.
- [34]Lglauer S,Wu Y.Alkyl polyglycoside surfactants for im-proved oil recovery[C].SPE 89472,2004.
- [35]Chen Hong,Han Lijuan,Luo Pingya.The ultralow interfa-cial tensions between crude oils and Gemini surfactant so-lutions[J].Journal of Colloid and Interface Science,2005(285):872-874.
- [36]谭中良,韩冬.阴离子孪连表面活性剂的合成及其界面活性研究[J].化学通报,2006,7:493-497.
- [37]杨颖,李明远,林梅钦.非离子型Gemini表面活性剂的表面活性与固液界面吸附特性研究[J].中国石油大学学报:自然科学版,2006,30(3):123-125.
- [38]朱森,程发,郑宝江.Gemini阴离子表面活性剂水溶液的界面活性[J].应用化学,2005,22(7):792-795.
- [39]吴江勇,于芳,吴巍.氨基磺酸两性Gemini的制备及驱油性能[J].研发前沿,2009,17(21):25-27.
- [40]郭丽梅,武首香,熊开琴.双子双酯硫酸钠的合成及性能[J].日用化学工业,2006,36(1):15-17.
- [41]刘冰妮,葛启,刘燕军.二辛基低聚二醇合成工艺初探[J].天津工业大学学报,2004,23(3):46-48.
- [42]李干佐,牟建海,陈锋.天然混合羧酸盐在三次采油和稠油降粘中的应用[J].石油炼制与化工,2002,33(9):25-28.
- [43]徐军,孙文起,李干佐,等.DSB显著提高羧酸盐驱油体系抗钙镁离子能力的研究[J].高等学校化学学报,2007,28(3):496-501.
- [44]Wang D M,Liu C D,Wu W X,et al.Development of anultra-low interfacial tension surfactant in a system with no-alkali for chemical flooding[C].SPE 109017,2008.
- [45]Mannhardt K,Novosad J J,Jha K N.Adsorption of foam-forming surfactants in berea sandstone[J].The Journal ofCanadian Petroleum Technique,1994,33(2):34-43.
- [46]Wormuth K R.Phase behavior of branched surfactants inoil and water[J].Langmuir,1997,2:2048-2053.
- [47]朱友益,沈平平,曲景奎,等.三次采油用烷基苯磺酸盐结构与性能的关系研究[J].石油勘探与开发,2004,31:9-12.
- [48]William A GoddradⅢ,Tang Yongchun.Lower cost methods for improved oil recovery via surfactant flooding[R].DE-FC26-01BC1562,2004.
- [49]曹绪龙.低浓度表面活性剂-聚合物二元复合驱油体系的分子模拟与配方设计[J].石油学报(石油加工),2008,24(6):682-688.
- [50]Skauge A,Palmgren O.Phase behavior and solution prop-erties of ethoxylated anionic surfactants[C].SPE 18499,1989.
- [51]化学驱提高石油采收率[M].杨普华,杨承志,译.北京:石油工业出版社,1998:49.
- [52]谭晶,曹绪龙,李英,等.油/水界面表面活性剂的复配协同机制[J].高等学校化学学报,2009,30(5):949-953.